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Study of arsenic in Famille rose porcelain from the Imperial Palace of Qing Dynasty, Beijing, China
Li, Yuanqiu1,2; Zhu, Jian1,2; Ji, Luoyuan3; Shan, Yingying3; Jiang, Sheng4; Chen, Guang5,6; Sciau, Philippe7; Wang, Wenxuan1,2; Wang, Changsui1,2
2018-02-01
发表期刊CERAMICS INTERNATIONAL
卷号44期号:2页码:1627-1632
文章类型Article
摘要Famille rose porcelain from the imperial workshop was one of the symbols of the highest level of manufacturing techniques in ancient China. It was very precious and only owned by the royals at the early stage. The major feature of famille rose is the use of opaque white pigment. Considered to originate in Europe, this technique was a witness of technological exchanges between China and European countries in the 17th-18th centuries. However, limited by its preciousness, most of the previous studies focused on the chemical composition of famille rose relics via nondestructive analysis methods. In this work, selected samples excavated at the Forbidden City of China were analysed by microscopy observation, Laser Ablation Inductive Coupled Plasma-Atomic Emission Spectrometry (LA-ICP-AES), synchrotron radiation X-ray Absorption Near-Edge Spectroscopy (XANES) and micro X-ray Diffraction (pXRD). The results revealed that two painting methods which related to Chinese and European techniques were applied. Chemical composition indicate that opaque white is a kind of arsenic-lead white. Moreover, the synchrotron radiation results show that As5+ is the major state in opaque white and exists mostly probably as AsO43- -ion.
关键词X-ray Methods Colour Porcelain Arsenic-lead White
WOS标题词Science & Technology ; Technology
DOI10.1016/j.ceramint.2017.10.084
关键词[WOS]INFRARED MICROSCOPY ; SYNCHROTRON ; ANCIENT ; POTTERY ; XANES ; RAMAN ; SOIL
收录类别SCI
语种英语
项目资助者National Natural Science Foundation of China(11275265 ; National Social Science Foundation of China(15BKG005) ; fund of the distinguished young scientists on history of sciences by bureau of frontier sciences and education, Chinese Academy of Sciences(Y529023EA2) ; UCAS Joint Ph.D.Training Program(UCAS[2015]37) ; U1432243)
WOS研究方向Materials Science
WOS类目Materials Science, Ceramics
WOS记录号WOS:000418211600052
引用统计
文献类型期刊论文
条目标识符http://119.78.100.205/handle/311034/8063
专题中科院古脊椎所(2000年以后)
作者单位1.Chinese Acad Sci, Inst Vertebrate Paleontol & Paleoanthropol, Key Lab Vertebrate Evolut & Human Origins, Beijing 100044, Peoples R China
2.Univ Chinese Acad Sci, Dept Archaeol & Anthropol, Beijing 100049, Peoples R China
3.Palace Museum Archaeol Inst, Beijing 100009, Peoples R China
4.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China
5.Anhui Univ, Inst Hlth Sci, Hefei 230601, Anhui, Peoples R China
6.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China
7.Toulouse Univ, CNRS, CEMES, F-31055 Toulouse, France
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GB/T 7714
Li, Yuanqiu,Zhu, Jian,Ji, Luoyuan,et al. Study of arsenic in Famille rose porcelain from the Imperial Palace of Qing Dynasty, Beijing, China[J]. CERAMICS INTERNATIONAL,2018,44(2):1627-1632.
APA Li, Yuanqiu.,Zhu, Jian.,Ji, Luoyuan.,Shan, Yingying.,Jiang, Sheng.,...&Wang, Changsui.(2018).Study of arsenic in Famille rose porcelain from the Imperial Palace of Qing Dynasty, Beijing, China.CERAMICS INTERNATIONAL,44(2),1627-1632.
MLA Li, Yuanqiu,et al."Study of arsenic in Famille rose porcelain from the Imperial Palace of Qing Dynasty, Beijing, China".CERAMICS INTERNATIONAL 44.2(2018):1627-1632.
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